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Updated: Sep 9, 2025

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron
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Published on: August 12, 2019

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ホモレプティックな鉄サロックス複合体によって触媒化されたエナンチオセレクティブC-Hアミネーション

Wowa Stroek1, Nathalie A V Rowlinson1, Luke A Hudson1

  • 1Department of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, CH-3012 Bern, Switzerland. martin.albrecht@unibe.ch.

Chemical communications (Cambridge, England)
|September 5, 2025
PubMed
まとめ

サリチロキサゾリンのリガンドを持つキラル鉄触媒は,アルキルアジドのエナチオセレクティブC-Hアミネーションを可能にします. この研究は,アリファティックC-H結合の最初の触媒アミネーションを実証し,C-H機能化の範囲を拡大した.

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