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Updated: Sep 8, 2025

Characterization, Quantification and Compound-specific Isotopic Analysis of Pyrogenic Carbon Using Benzene Polycarboxylic Acids BPCA
08:12

Characterization, Quantification and Compound-specific Isotopic Analysis of Pyrogenic Carbon Using Benzene Polycarboxylic Acids BPCA

Published on: May 16, 2016

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化合物特有の安定した炭素とブローム同位体分析 オーガノブロミン汚染物質の変換メカニズムを追跡する:原理,方法論,応用のレビュー

Haoyu Zeng1, Songsong Chen2, Xiao Liu3

  • 1State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China. lmma@tongji.edu.cn.

Environmental science. Processes & impacts
|September 5, 2025
PubMed
まとめ

炭素とブロームの同位体を用いた化合物固有の安定同位体分析 (CSIA) は,有機ブロミン汚染物質の分解を追跡する. この方法は,汚染物質の変換経路を明らかにし,環境リスクの評価と管理を支援します.

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Halogenation of Alkenes02:46

Halogenation of Alkenes

Halogenation is the addition of chlorine or bromine across the double bond in an alkene to yield a vicinal dihalide. The reaction occurs in the presence of inert and non-nucleophilic solvents, such as methylene chloride, chloroform, or carbon tetrachloride.
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Chlorination and bromination are important classes of electrophilic aromatic substitutions, where benzene reacts with chlorine or bromine in the presence of a Lewis acid catalyst to give halogenated substitution products. A Lewis acid such as aluminium chloride or ferric chloride catalyzes the chlorination, and ferric bromide catalyzes the bromination reactions. During the bromination of alkenes, bromine polarizes and becomes electrophilic. However, in the bromination of benzene, the bromine...
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