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Updated: Sep 8, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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三重カルベンの挿入は,C2-置換されたビサイクロ[1.1.1]ペンタンのモジュールアクセスを可能にします

Jin-Teng Che1, Hong-Bo Zhang1, Wei-Yi Ding1

  • 1Shenzhen Grubbs Institute, Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China.

Journal of the American Chemical Society
|September 5, 2025
PubMed
まとめ

私たちは,C2-置換されたビサイクロ[1.1.1]ペンタン (BCP) を,ビサイクロ[1.1.0]ブタンとディアゾ化合物を使用して合成する新しい方法を開発しました. このアプローチは新しい3D化学構造へのアクセスを提供し,15の生物活性分子に適用されています.

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