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Updated: Jan 18, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

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液体対液体相分離による結合ポリマーの普遍的なキラル対称性分解

Zhuang Xu1, Ziming Wang1, Rui Zhang1

  • 1Department of Chemical and Biomolecular Engineering, Department of Chemistry, Department of Materials Science and Engineering, Beckman Institute for Advanced Science and Technology, University of Illinois Urbana-Champaign,Urbana, Illinois 61801, United States.

Journal of the American Chemical Society
|September 8, 2025
PubMed
まとめ

科学において重要なキラル対称性破裂は,エントロピー駆動液相分離 (LLPS) を通して,非キラルポリマーで自発的に発生する. この発見は 生命の起源を理解する キラル・エレクトロニクスに 新たな道を開きます

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Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
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Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
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