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Updated: Jan 18, 2026

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
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Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions

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光触媒 H2O2生産のための共性有機フレームワークの酵素クリック後合成改変

Quan Zuo1, Bingxian Chu1, Xinhe Ye1

  • 1Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM), SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL), Guangdong-Hongkong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices and Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China.

Journal of the American Chemical Society
|September 11, 2025
PubMed
まとめ

合成後の酵素改変 (PSM) は,共性有機フレームワーク (COF) の効率的な機能化を可能にします. この新しいアプローチは,電荷分離と陽子の供給を改善することによって,光触媒性過酸化水素の生産を向上させます.

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Catalysis02:50

Catalysis

The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
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