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ドナーリガンドのない二酸化窒素複合体: [Mn(CO) 5<η1-N2) ]+塩の分離と特徴づけ

Malte Sellin1, James D Watson2, Julia Fischer1

  • 1Institut für Anorganische und Analytische Chemie and Freiburg Materials Research Center FMF, Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany.

Journal of the American Chemical Society
|September 13, 2025
PubMed
まとめ

研究者らは,電子受容体として作用する新しい二酸化窒素複合体[Mn(CO) 5(η1-N2) ]+を合成した. この発見は,金属複合体におけるダイナトロゲンリガンドの行動に関する以前の理解に異議を唱えている.

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