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Updated: Jan 17, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
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効率的なアルカリ水素進化のための単原子合金ナノケージの相調合成

Wenbin Jiang1, Song Lin Zhang2, Jing Yang3

  • 1Department of Materials Science and Engineering, National University of Singapore, Singapore 117575, Singapore.

Journal of the American Chemical Society
|September 21, 2025
PubMed
まとめ

研究者は,アルカリ溶液における効率的な水素進化反応 (HER) のためのユニークな結晶相を持つ超薄プラチナ・ルテニウム (Pt-Ru) ナノケージを開発し,商業的触媒よりも18倍高い活性を示した.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
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