結晶のアリリミノフォスフィニルラジカル:アリルディアゼニルラジカルのリン原産

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Updated: Jan 16, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI

Published on: November 22, 2016

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Xu Wang1, Yizhen Chen1, Xinyi Li1

  • 1Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-sen University, Guangzhou 510275, China.

Journal of the American Chemical Society
|October 4, 2025
PubMed
まとめ

研究者らは安定したアリミノフォスフィニル基 (Ar-NP) を合成し,一時的なアリルディアゼニル基のより重たい類型である. を中心としたこの新種のラジカルは 独特の反応性を発揮し 還元時に前例のないアニオン塩を形成します

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