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Updated: Jan 15, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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HAT-プライムされたC-Sラジカル-ラジカルカップリングによるアレンのC-H非対称性サルフィリン化

Yishou Wang1,2, Yucai Mu3, Xin Han2

  • 1Institute of Chemistry Frontier, School of Chemistry and Chemical Engineering, Shandong University, Qingdao 266237, China.

Journal of the American Chemical Society
|October 7, 2025
PubMed
まとめ

この研究は, (ヘテロ) アレンとスルフェナミドからキラル・スルフィリミンを合成するための効率的な銅触媒法を示している. この新しいアプローチは,温和な条件下で高い選択性を達成し,これらの重要な機能的分子を作るための貴重なツールを提供します.

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In organic synthesis, the formation of products can be altered by changing the reaction conditions. For example, a dibromo addition product is formed when propene is treated with bromine at room temperature. In contrast, propene undergoes allylic substitution in non-polar solvents at high temperatures to give 3-bromopropene. In order to avoid the addition reaction, the bromine concentration must be kept as low as possible throughout the reaction. This can be achieved using N-bromosuccinimide...
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