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Updated: Jan 6, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

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ニッケル ((0)) /フォスフィン触媒によるCO2とサイクロヘキシラレンを分解可能な長鎖ポリエステルに共聚する

Xi Liao1, Xiaoyan Tang1

  • 1Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.

Journal of the American Chemical Society
|November 27, 2025
PubMed
まとめ

この研究では,炭素二酸化物 (CO2) をポリマーで効率的に共ポリマー化するための新しいコモノメールとしてサイクロヘキシラレン (CA) が導入されています. この突破により CO2 ベースの高度なポリエステルが作られ,分解性と熱安定性が向上しました.

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