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Updated: Jan 9, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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ディエネ覆いカルベン:サイクル添加,共聚合,および触媒への経路

Mamak Bakhtiari1, Ludwig Zapf1, Tanja Kunz1

  • 1Department of Chemistry, University of Alberta, 11227 Saskatchewan Dr., Edmonton, Alberta T6G 2G2, Canada.

Journal of the American Chemical Society
|December 10, 2025
PubMed
まとめ

新たに合成され,機能化された新型ダイーン覆いカルベン (DECC) が開発された. そのフォスフィニデン複合体は,サイクロアディション反応を可能にし,金活性化アルキン水分化前触媒として作用する天然ゴム型コポリマーを形成する.

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