白酒陈酿过程中挥发性香气成分的演变追踪:温度、氧气和陶罐影响的定量见解
Lulu Wang1, Tengfei Zhao2, Yehui Han3
1School of Brewing Engineering, Moutai Institute, Renhuai 564501, China; State Key Laboratory of Food Science & Technology, Key Laboratory of Industrial Biotechnology of Ministry of Education & School of Biotechnology, Jiangnan University Wuxi, Jiangsu 214122, China; Kweichow Moutai Group, Renhuai 564501, China.
Abstract:
This study elucidated microenvironmental regulation of aroma compound evolution in Baijiu through a multifactorial aging study. Quantitative analysis of 139 volatile compounds employed multimodal extraction coupled with GC-MS/GC × GC-TOFMS. PLS-DA indicated significant sample divergence across factors. Spearman correlation/network visualization revealed pottery-associated modulation of 54 compounds, temperature-driven dynamics in 47 compounds, and oxygen-dependent regulation of 18 compounds. Elevated storage temperature significantly reduced esters, terpenes, aldehydes, and ketones, while elevated dissolved oxygen accelerated ester degradation and sulfur compound interconversions. High temperature (>35 °C) promoted ester hydrolysis and the reduction of aldehydes and ketones; oxygen selectively oxidized methanethiol to dimethyl disulfide and dimethyl trisulfide. Storage with pottery chips enhanced accumulation of furans, pyrazines, and sulfur compounds, likely catalyzed by clay-derived metal ions. Variance partitioning analysis identified storage duration (10 %), followed by temperature (9 %), pottery (4 %), and oxygen (1 %). The hierarchical framework clarifies multifactorial modulation of aroma evolution, offering technical insights for optimizing artisanal spirit aging.
さらに関連する動画
09:12Optimization of Processing of Tiebangchui with Highland Barley Wine Based on the Box-Behnken Design Combined with the Entropy Method
Published on: May 19, 2023
08:43PTR-ToF-MS Coupled with an Automated Sampling System and Tailored Data Analysis for Food Studies: Bioprocess Monitoring, Screening and Nose-space Analysis
Published on: May 11, 2017
関連する概念動画
Volatilization
Distillation: Vapor–Liquid Equilibria
Drug Product Stability
Effect of Temperature Change on Reaction Rate
Atomic Spectroscopy: Effects of Temperature
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature...
Vapor Pressure
