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Updated: Jan 8, 2026

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Warisha Tahir1, Yuqin Wei2, Mao Wang2

  • 1Department of Chemistry, Functional Materials, Technische Universität Berlin, 10623 Berlin, Germany.

Journal of the American Chemical Society
|December 23, 2025
PubMed
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No abstract available in PubMed .

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Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
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