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関連する概念動画

Redox Equilibria: Overview01:23

Redox Equilibria: Overview

1.5K
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
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Redox Reactions01:24

Redox Reactions

58.1K
Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
58.1K
Redox Reactions01:27

Redox Reactions

832
Redox reactions are vital biochemical processes that underpin energy metabolism in cells. These reactions involve the transfer of electrons between molecules, occurring in tandem as oxidation and reduction. Oxidation refers to the loss of electrons, while reduction denotes their gain. This coupling ensures the seamless flow of electrons through metabolic pathways. For example, in bacterial metabolism, glucose undergoes oxidation to carbon dioxide, while oxygen is simultaneously reduced to...
832
Oxidation-Reduction Reactions03:11

Oxidation-Reduction Reactions

74.8K
Oxidation–Reduction Reactions
74.8K
Oxidation and Reduction of Organic Molecules01:19

Oxidation and Reduction of Organic Molecules

9.0K
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
9.0K
Redox Titration: Other Oxidizing and Reducing Agents01:26

Redox Titration: Other Oxidizing and Reducing Agents

1.3K
Besides iodine, other oxidizing or reducing agents can serve as titrants in redox titrations. Common oxidizing titrants include KMnO4, cerium(IV), and K2Cr2O7. The choice of oxidizing titrants depends on factors like stability, cost, analyte strength, and reaction rate between the analyte and titrant. KMnO4 is a strong oxidizing titrant that reduces from Mn(VII) to Mn(II) in a highly acidic solution, simultaneously oxidizing the analyte to a higher oxidation state. In this case, KMnO4 acts as a...
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関連する実験動画

Updated: Jan 8, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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レドックス活性メソポーラスコバルト-ピラゾラート骨格による可逆的O₂吸着

Yong-Zheng Zhang1,2, Tao He1, Xiang-Jing Kong1

  • 1Department of Chemical Engineering, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China.

Angewandte Chemie (International ed. in English)
|December 24, 2025
PubMed
まとめ
この要約は機械生成です。

研究者らは、新規メソポーラスピラゾラート金属有機構造体(MOF)であるBUT-45を開発しました。この材料は、活性コバルトサイトにより可逆的な酸素化学吸着を示し、触媒およびガス貯蔵用のMOF設計を前進させます。

キーワード:
脱対称化メソポーラス金属有機構造体ピラゾラート配位子可逆的O₂吸着

さらに関連する動画

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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関連する実験動画

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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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科学分野:

  • 材料科学
  • 化学
  • ナノテクノロジー

背景:

  • ピラゾラート金属有機構造体(MOF)は、カルボキシラート類似体と比較して、ガス貯蔵、分離、触媒において優れた化学的安定性と性能を提供します。
  • M-N結合によって課される幾何学的制約のため、ピラゾラートMOFにメソポーロシティと活性サイトを統合することは合成的に困難です。
  • ピラゾラートMOFの構造的多様性の制限は、その潜在的な応用を制限します。

主な方法:

  • 網目化学を利用して、csq型ピラゾラートMOFであるBUT-45を構築しました。
  • 合成には、低対称性のテトラピラゾラート配位子(CTP4-)と8配位のCo6クラスターを使用しました。
  • 単結晶X線回折とin situ分光法を用いて、材料の構造と酸素との相互作用を分析しました。

結論:

  • 網目化学は、カルボキシラートからピラゾラートMOFへのターゲットネットのマッピングに成功し、新しい構造を可能にします。
  • BUT-45は、安定性が向上したガス貯蔵および触媒用のピラゾラートMOFの可能性を示しています。
  • MOFにおけるレドックス化学の直接的な可視化は、触媒メカニズムへの洞察を提供します。