関連する実験動画

Updated: Jan 7, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Published on: March 20, 2014

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パラジウム(II)ジクロリドにおける分子内水素結合の設計

Karli D Sipps1, Hemant P Yennawar2, Jonathan L Kuo1

  • 1Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania16802, United States.

Inorganic chemistry
|December 28, 2025
PubMed
まとめ

Pd(II)ジクロリドにおける分子内水素結合の設計は、配座解析によって達成される。不飽和の6員環メタラサイクルの柔軟性は、小さな再配列エネルギーによりこれらの結合を受け入れることができる。

キーワード:
分子内水素結合パラジウム(II)ジクロリド配座解析メタラサイクル柔軟性再配列エネルギー

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