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研究分野エンジニアリング化学工学エネルギーと燃焼における化学的および熱的プロセス
メタンの効率的で安定した光熱乾燥リフォーミングのためのRu/BaTiO₃に対する光熱誘導レイチス酸素流出

メタンの効率的で安定した光熱乾燥リフォーミングのためのRu/BaTiO₃に対する光熱誘導レイチス酸素流出

Delong Duan ¹, Cenfeng Fu ², Xiaomin Ji ¹, Zehui Dai ¹, Aobo Chen ¹, Canyu Hu ¹, Min Ge ³, Hailong Xiong ^1,4, Min Zhou ¹, Ran Long ¹, Yujie Xiong ^1,4

Delong Duan ¹, Cenfeng Fu ², Xiaomin Ji ¹

¹Hefei National Research Center for Physical Sciences at the Microscale, Key Laboratory of Precision and Intelligent Chemistry, School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026, China.
²School of Materials Science and Engineering, Hefei University of Technology, Hefei , Anhui 230009, China.
³The Instruments Center for Physical Science, University of Science and Technology of China, Hefei 230026, China.
⁴Anhui Engineering Research Center of Carbon Neutrality, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, China.

⁰Hefei National Research Center for Physical Sciences at the Microscale, Key Laboratory of Precision and Intelligent Chemistry, School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026, China.

Journal of the American Chemical Society +

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2025年12月29日

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CO₂ Photoreduction to CH₄ Performance Under Concentrating Solar Light

Published on: June 12, 2019

A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration

A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration

Published on: March 29, 2019

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain

Published on: March 27, 2018

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まとめ

No abstract available on PubMed

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CO<sub>2</sub> Photoreduction to CH<sub>4</sub> Performance Under Concentrating Solar Light

CO₂ Photoreduction to CH₄ Performance Under Concentrating Solar Light

Published on: June 12, 2019

A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration

A Facile Synthetic Method to Obtain Bismuth Oxyiodide Microspheres Highly Functional for the Photocatalytic Processes of Water Depuration

Published on: March 29, 2019

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain

Published on: March 27, 2018

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関連する概念動画

Hydroboration-Oxidation of Alkenes

Hydroboration-Oxidation of Alkenes

In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.

Borane as a reagent is very reactive, as the...

Regioselectivity and Stereochemistry of Hydroboration

Regioselectivity and Stereochemistry of Hydroboration

A significant aspect of hydroboration–oxidation is the regio- and stereochemical outcome of the reaction.
Hydroboration proceeds in a concerted fashion with the attack of borane on the π bond, giving a cyclic four-centered transition state. The –BH2 group is bonded to the less substituted carbon and –H to the more substituted carbon. The concerted nature requires the simultaneous addition of –H and –BH2 across the same face of the alkene giving syn stereochemistry.

The observed...

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