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Updated: Jan 7, 2026

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低温熱処理は,O2型リチウム豊富なマンガン基材料の構造的安定性を高める

Yufang Chen1, Xiao Zhang1, Peitao Xiao1

  • 1Department of Materials Science and Engineering, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha, Hunan 410000, China. chenyufang@nudt.edu.cn.

Chemical communications (Cambridge, England)
|January 2, 2026
PubMed
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No abstract available in PubMed .

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Radical Oxidation of Allylic and Benzylic Alcohols01:21

Radical Oxidation of Allylic and Benzylic Alcohols

Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
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