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Updated: Jan 13, 2026

Manganese Oxide Nanoparticle Synthesis by Thermal Decomposition of ManganeseII Acetylacetonate
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Manganese Oxide Nanoparticle Synthesis by Thermal Decomposition of ManganeseII Acetylacetonate

Published on: June 18, 2020

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超安定酸性酸素進化触媒のためのRu-Doped Mn3O4のナノシールドの電気化学的形成

Haoqiang Song1, Jingkun Yu1, Mingjun Nie1

  • 1College of Chemistry, Pingyuan Laboratory, Zhengzhou University, Zhengzhou 450000, China.

Journal of the American Chemical Society
|January 6, 2026
PubMed
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No abstract available in PubMed .

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Radical Oxidation of Allylic and Benzylic Alcohols01:21

Radical Oxidation of Allylic and Benzylic Alcohols

Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
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