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Updated: Jan 13, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

有機ケージビルディングブロックを用いたhmcトポロジーを持つ金属有機構造体の構築における網状化学的アプローチ

Lin Lin¹, Zihao Wang¹, Xinhui Zhao¹

¹Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, China. jiangtaojia@nenu.edu.cn.

Chemical communications (Cambridge, England)

|January 7, 2026

Abstract:

A molecular design strategy for constructing metal-organic frameworks (MOFs) from preorganized organic cage building blocks is presented. Two frameworks, MOF-POC-1 and MOF-POC-2, were synthesized and found to crystallize in the cubic Fm3̄m space group, adopting an hmc topology generated by using 6-connected carboxylic acid organic cages as building blocks. Notably, MOF-POC-2 was observed to exhibit intrinsic porosity and gas adsorption, highlighting the potential of employing pre-organized organic cages as modular components for the rational design of highly symmetric, porous MOFs with tunable functionalities.

キーワード:

金属有機構造体有機ケージ網状化学 hmcトポロジー多孔質材料

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