脆性-強固転移の実験的非証拠
Petr Koštál1, Jaroslav Barták2, Michaela Včeláková1
1Department of Inorganic Technology, University of Pardubice, Doubravice 41, 53210 Pardubice, Czech Republic.
まとめ
ゲルマニウム-セレン(Ge-Se)ガラスの粘性は、広い範囲にわたって研究されました。研究者らは、これらのカルコゲナイドガラス形成系において、脆性-強固転移の証拠がないことを発見しました。
科学分野:
- 材料科学
- 固体化学
- ガラス科学
背景:
- カルコゲナイドガラス、特にGe-Se系は技術的に重要です。
- それらの粘性を理解することは、加工と応用のために重要です。
- 脆性-強固転移の有無は、ガラス特性に影響します。
主な方法:
- 5-20 at.% Geの4つのGe-Seガラス組成を合成しました。
- 粘性を約13桁にわたって測定しました。
- 圧力支援溶融充填と浸透および平行板粘度測定を組み合わせました。
結論:
- Ge-Seガラス系は脆性-強固転移を示しません。
- 粘性測定は、これらのカルコゲナイドガラスのユニークな流れ挙動を確認します。
- さらなる研究は、材料加工およびデバイス製造への影響を探求することができます。
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