界面における混合原子価Cu(II)/Cu(III)エネルギーMOFの電子変調による二官能触媒：過塩素酸アンモニウム熱分解の強化とCO2電気化学的還元の効率化

The development of multifunctional catalytic platforms that reconcile high energy density with environmental sustainability presents a significant challenge in materials science. Herein, we report a rare mixed-valence Cu(II)/Cu(III) energetic metal-organic framework (EMOF), {[Cu(II)Cu(III)₂(HBTT)(BTT)Cl₃(H₂O)₄]·H₂O}_n (denoted as CuBTT), as a dual-functional catalyst for both ammonium perchlorate (AP) thermolysis and electrochemical CO₂ reduction (ECO₂R). CuBTT exhibits remarkable structural robustness, thermal safety, and low sensitivity, enabling practical deployment. The dual catalytic prowess originates from its special mixed-valence Cu(II)/Cu(III) interfaces, which enable efficient interfacial electron modulation and stepwise electron transfer tailored to the specific demands of each reaction. This unique mechanism, unequivocally validated by X-ray photoelectron spectroscopy (XPS) analysis, demonstrates distinct redox behaviors: in AP thermolysis, CuBTT acts as a multielectron redox shuttle, dramatically lowering the high-temperature decomposition (HTD) peak by 127.2 °C and boosting the total heat release by 81.6%; in ECO₂R, its dynamic valence cycling facilitates C-C coupling, achieving high Faradaic efficiencies for CO (42.4%), C₂H₅OH (23.4%), and CH₄ (3.3%) at -0.6 V vs RHE. CuBTT also demonstrates excellent stability (>60 h) and rapid kinetics (Tafel slope: 69 mV dec^-1). This work highlights valence engineering via interfacial electron modulation as a powerful strategy for designing multifunctional materials and positioning CuBTT as a promising platform for sustainable energy and environmental applications.