広温度域水系金属電池における電解質配位環境：メカニズムと設計戦略

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Updated: Jan 13, 2026

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

Jiashuo Zhang^1,2, Tao Liu^1,2, Xusheng Dong^1,2

¹Interdisciplinary Research Center for Sustainable Energy Science and Engineering (IRC4SE2), Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University Zhengzhou 450001 Henan China rzzhao@zzu.edu.cn.

Chemical science

|January 12, 2026

Abstract:

Aqueous metal batteries (AMBs) are promising for energy storage, which is attributed to their intrinsic safety, low cost, and environmental friendliness. However, they degrade at extreme temperatures, i.e., they undergo crystallization at low temperatures and evaporation or heat-driven side reactions at high temperatures, which have raised performance and safety concerns. Addressing these challenges requires simultaneous thermodynamic and kinetic insights into electrolyte behavior under such conditions. Among various strategies, tuning intermolecular interactions to optimize the electrolyte coordination environment has been proven to be especially effective. However, comprehensive treatments that integrate both low- and high-temperature regulation and provide underlying electrochemical mechanisms remain scarce. This review (i) dissects the failure modes of AMBs under extreme temperature conditions, (ii) discusses advances related to molecular-interaction tuning for wide-temperature performance, and (iii) offers perspectives and design guidelines for future research and development.

キーワード:

水系金属電池電解質配位環境広温度域エネルギー貯蔵劣化メカニズム分子間相互作用

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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Published on: August 12, 2013

Rapid in-silico Battery Electrolyte Electrochemical Reaction Generation using 3T-VASP Multi-Scale Energy Minimization

Rapid in-silico Battery Electrolyte Electrochemical Reaction Generation using 3T-VASP Multi-Scale Energy Minimization

Published on: August 22, 2025

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