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Updated: Jan 14, 2026

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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カテラニにインスパイアされたBN-アロマティック拡張:調節可能な光感受性を持つπ-拡張1,2-アザボリンのための汎用ツール

Federica Rulli1, Sergi Ordeix1, Roger Bresolí-Obach1

  • 1Institut Químic de Sarrià, Universitat Ramon Llull, Vía Augusta 390, 08017 Barcelona, Spain.

Journal of the American Chemical Society
|January 12, 2026
PubMed
まとめ

ボロン-窒素 (BN) 同位体は新しい有機化合物を可能にします. この研究は,BNユニットの方向性を制御することによって調節可能な光誘発単片酸素生成を実証する拡張BNポリアロマティックコアを合成する方法を導入します.

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para...
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