ニッケルフォーム上の階層的CoMoP/NiCoPヘテロ構造による、工業的電流密度での効率的な硝酸塩からアンモニアへの電気化学的変換
Min Xu1,2, Shengbo Zhang1,2, Hui Xu1,2
1Key Laboratory of Materials Physics, Centre for Resource Innovation, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, Anhui, China. hxu@issp.ac.cn.
Abstract:
Here we construct a CoMoP/NiCoP hierarchical heterostructure on nickel foam as an integral electrode, achieving a remarkable nitrate-to-ammonia faradaic efficiency of 94.9% at -0.4 V (vs. RHE) and a production rate of 88.6 mg h-1 cm-2. This superior performance could be due to the electron transfer from Mo to Co/Ni through P mediation, resulting in enhanced NH3 electrosynthesis kinetics and selectivity.
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