効率的な光熱電変換のためのヘキサアザトリナフチレン系近赤外光熱有機小分子
Ning-Ning Zhang1,2, Wei-Li Zheng1, Lin-Xu Liu1
1School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252000, P. R. China. zhangningning@lcu.edu.cn.
Abstract:
5,6,11,12,17,18-Hexaazatrinaphthylene-2,8,14-tricarboxylic acid (HTA) exhibits broad absorption (300-1500 nm) and a high PCE (>60%), attributed to the formation of stable triplet diradicals via intramolecular charge transfer. Remarkably, the HTA@TEC1-12701 device outputs 211.9 mV under 1 sun and 930 mV under 4 suns, sufficient to drive a small fan.
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