ZnMgLi(Dy, Ho, Er, Tm)系における原始的な正二十面体型準結晶
Ireneusz Buganski1, Stanislav Vrtnik2, Radoslaw Strzalka1
1Faculty of Physics and Applied Computer Science, AGH University of Krakow, Al. Mickiewicza 30, Krakow, 30-059, Poland.
Abstract:
New quasicrystals with rare-earth elements and Li are synthesized with the self-flux method. The starting composition involves 62.8 at.% Zn, 28.6 at.% Mg, 3.6 at. % rare-earth and 5% Li. Alternatively, 66 at.% Zn, 24.8 at.% Mg, 3.9 at.% rare-earth and 5.3% Li can be used. Both syntheses result in quasicrystals exhibiting differences in the quasilattice constant which is additionally correlated with the size of the rare-earth atom. Monocrystal X-ray diffraction reveals that Li substitutes the rare-earth element found in the center of the Tsai cluster. The substitution of Li for the rare-earth element not only changes the electron-to-atom ratio but also changes the distribution of magnetic-moment-bearing elements which can affect magnetic properties.
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