非水酸化水素酸化のための単一原子ニッケルプロモーターによる表面変調白金電極触媒
Kuiquan Yan1,2, Yang Hong1,2, Zhi Wang1,2
1State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, No. 5625, Renmin Street, Chaoyang District, Changchun, 130022, P.R. China.
Angewandte Chemie (International ed. in English)
|January 22, 2026
まとめ
単一原子のNiをPtサイトにドープすることは、有機電解質中の水素酸化反応（HOR）を強化する。この新しい触媒（PtNi1/Ni）は、電気化学的アンモニア合成における課題を克服し、高い効率と安定性を示す。
背景:
- 水素酸化反応（HOR）は再生可能エネルギー変換に不可欠です。
- 非水電解質における課題には、遅い速度論と触媒被毒が含まれます。
- HORは、リチウム媒介窒素還元と組み合わされた電気化学的アンモニア合成に不可欠です。
結論:
- 単一原子ドーピングは、活性で耐久性のある非水HOR電極触媒を作成するための効果的な戦略です。
- PtNi1/Niは、相乗効果により優れた抗被毒特性を示します。
- この触媒は、約62%の高いアンモニアFEで電気化学的アンモニア合成に有望です。
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