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Updated: Jan 25, 2026

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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Published on: July 17, 2020

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アンビモダル (2 + 1) / 4 + 1) ディハロカルベンとオレフィン間の反応における擬似循環的移行状態

Tongkun Wang1, Xiao-Song Xue1

  • 1State Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials and Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai 200032, China.

Journal of the American Chemical Society
|January 24, 2026
PubMed
まとめ

研究者らは,カルベンの反応において,アンビモダル (2+1) / 4+1) の擬似回転状態を発見した. この発見は,これらの新しい化学変換における反応経路とダイナミクスが製品の選択性をどのように制御するかを説明します.

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