Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

RNA Stability01:53

RNA Stability

35.7K
Intact DNA strands can be found in fossils, while scientists sometimes struggle to keep RNA intact under laboratory conditions. The structural variations between RNA and DNA underlie the differences in their stability and longevity. Because DNA is double-stranded, it is inherently more stable. The single-stranded structure of RNA is less stable but also more flexible and can form weak internal bonds. Additionally, most RNAs in the cell are relatively short, while DNA can be up to 250 million...
35.7K
Nuclear Stability03:18

Nuclear Stability

23.2K
Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
To hold positively charged protons together...
23.2K
Stability01:28

Stability

415
The time response of a linear time-invariant (LTI) system can be divided into transient and steady-state responses. The transient response represents the system's initial reaction to a change in input and diminishes to zero over time. In contrast, the steady-state response is the behavior that persists after the transient effects have faded.
The stability of an LTI system is determined by the roots of its characteristic equation, known as poles. A system is stable if it produces a bounded...
415
Molecules and Compounds02:38

Molecules and Compounds

68.6K
Atoms and Molecules
68.6K
Stability of structures01:14

Stability of structures

519
In mechanical engineering, the stability of systems under various forces is critical for designing durable and efficient structures. One fundamental way to explore these concepts is by analyzing systems like two rods connected at a pivot point, O, with a torsional spring of spring constant k at the pivot point. This system is similar in appearance to a scissor jack used to change tires on a car. In this case, the arms of the linkage (equivalent to the rods in this system) are entirely vertical,...
519
Pole and System Stability01:24

Pole and System Stability

964
The transfer function is a fundamental concept representing the ratio of two polynomials. The numerator and denominator encapsulate the system's dynamics. The zeros and poles of this transfer function are critical in determining the system's behavior and stability.
Simple poles are unique roots of the denominator polynomial. Each simple pole corresponds to a distinct solution to the system's characteristic equation, typically resulting in exponential decay terms in the system's...
964

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Methanol Production from Aqueous Formaldehyde Using Ruthenium Imidazolylamine Complexes: Ligand-Tuned Selectivity.

Inorganic chemistry·2026
Same author

Carbodiborylenes: Computational Discovery of 1,3-Diboraallenes Capable of Multiple Complexation of CO<sub>2</sub> and CS<sub>2</sub>.

Inorganic chemistry·2026
Same author

Synthesis and Selective Carboboration Reactivity of a Flexible P-Stabilized Bromoborenium.

Inorganic chemistry·2026
Same author

Six-Membered Cyclic (Alkyl)(amino)silylenes for Dehydrogenation of Ammonia Borane, Hydrogenation of CO<sub>2</sub>, and Unsaturated Bonds.

Inorganic chemistry·2026
Same author

Low-Valent Group 14 Species Supported by BICAAC: Isolation of a Germylone and a Digermanium Compound.

Chemistry (Weinheim an der Bergstrasse, Germany)·2025
Same author

Theoretical prediction of metallomimetic stable cyclic group 13 carbenoids.

Dalton transactions (Cambridge, England : 2003)·2025

関連する実験動画

Updated: Jan 31, 2026

Activating Molecules, Ions, and Solid Particles with Acoustic Cavitation
14:22

Activating Molecules, Ions, and Solid Particles with Acoustic Cavitation

Published on: April 11, 2014

15.6K

モノ(シリル)-安定化ボリレンによる小分子活性化

Ashim Tamuli1, Ashwini K Phukan1

  • 1Department of Chemical Sciences, Tezpur University, Tezpur, Assam, India.

Chemistry (Weinheim an der Bergstrasse, Germany)
|January 30, 2026
PubMed
まとめ

研究者らは、シリル基によって安定化された新規ボリレンを設計し、COやN2などの小分子の活性化と結合における潜在能力を実証した。その性能は既存のボリレンと比較して競争力があるか、あるいは向上している。

科学分野:

  • 有機金属化学
  • 主族化学
  • 計算化学

背景:

  • 塩基安定化ボリレンは知られているが、単離可能なモノ(ルイス塩基)安定化誘導体はまれである。
  • シリル基は、反応性の高いホウ素種を安定化するための独自のルイス塩基特性を提供する。

研究 の 目的:

  • シリル基をルイス塩基として用いた新規モノ(ルイス塩基)安定化ボリレンの設計と調査。
  • 強いE-H結合の活性化および小分子の配位におけるそれらの可能性の評価。

主な方法:

  • 量子化学計算を用いて、ボリレンの電子特性を設計および分析した。
  • 計算研究により、E-H結合開裂(E = H、CH3、NHPh)の活性化障壁を評価した。
  • 一酸化炭素(CO)および二窒素(N2)の結合親和性を計算によって調査した。

主要な成果:

  • 設計されたボリレンは、顕著なドナーおよびアクセプター能力を示す。
  • 計算により、既知のボリレンと比較してE-H結合活性化において競争力のある、またはそれを上回る性能が示唆される。
  • COおよびN2分子の効果的な結合が計算によって実証された。

結論:

キーワード:
DFTEDA‐NOCV塩基安定化ボリレンシリル小分子活性化

さらに関連する動画

A Method of Permeabilization of Drosophila Embryos for Assays of Small Molecule Activity
10:04

A Method of Permeabilization of Drosophila Embryos for Assays of Small Molecule Activity

Published on: July 13, 2014

13.0K
An Improved Protocol to Purify and Directly Mono-Biotinylate Recombinant BDNF in a Tube for Cellular Trafficking Studies in Neurons
13:46

An Improved Protocol to Purify and Directly Mono-Biotinylate Recombinant BDNF in a Tube for Cellular Trafficking Studies in Neurons

Published on: July 11, 2020

6.3K

関連する実験動画

Last Updated: Jan 31, 2026

Activating Molecules, Ions, and Solid Particles with Acoustic Cavitation
14:22

Activating Molecules, Ions, and Solid Particles with Acoustic Cavitation

Published on: April 11, 2014

15.6K
A Method of Permeabilization of Drosophila Embryos for Assays of Small Molecule Activity
10:04

A Method of Permeabilization of Drosophila Embryos for Assays of Small Molecule Activity

Published on: July 13, 2014

13.0K
An Improved Protocol to Purify and Directly Mono-Biotinylate Recombinant BDNF in a Tube for Cellular Trafficking Studies in Neurons
13:46

An Improved Protocol to Purify and Directly Mono-Biotinylate Recombinant BDNF in a Tube for Cellular Trafficking Studies in Neurons

Published on: July 11, 2020

6.3K
  • 新規シリル安定化ボリレンは、多用途な反応中間体として有望である。
  • これらの設計されたボリレンは、小分子活性化および配位化学のための新しいプラットフォームを提供する。
  • 計算結果は、これらのシステムが既存の安定化ボリレンの反応性において、匹敵するかそれを超える可能性があることを示唆している。