Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Bond Energies and Bond Lengths02:49

Bond Energies and Bond Lengths

31.5K
Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, that is, the energy necessary to separate the bonded atoms. Separating any pair of bonded atoms requires energy — the stronger a bond, the greater the energy required to break it.
31.5K
Peptide Bonds02:43

Peptide Bonds

83.2K
A peptide bond covalently attaches amino acids through a dehydration reaction. One amino acid's carboxyl group and another amino acid's amino group combine, releasing a water molecule. The resulting bond is the peptide bond. The products that such linkages form are peptides. As more amino acids join this growing chain, the resulting chain is a polypeptide. Each polypeptide has a free amino group at one end. This end has the N-terminal, or the amino-terminal, and the other end has a free...
83.2K
Bonding in Metals02:32

Bonding in Metals

52.5K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
52.5K
Ionic Bonds00:42

Ionic Bonds

131.1K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
131.1K
Valence Bond Theory02:45

Valence Bond Theory

50.3K
Overview of Valence Bond Theory
50.3K
Valence Bond Theory02:42

Valence Bond Theory

11.3K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
11.3K

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Transition-Metal-Free Synthesis of Indolo[2,1-<i>a</i>]isoquinolines via Intramolecular Tandem Radical Cyclization.

The Journal of organic chemistry·2025
Same author

N-Heterocyclic Carbene Catalysis for Polycyclic Benzazepines Assembly: Regioselective Intramolecular Tandem Radical Cyclization.

Organic letters·2024
Same author

Defunctionalization Enabled by Intramolecular Radical Aromatic <i>Ipso</i> Substitution.

Organic letters·2024
Same author

Construction of Functionalized Oxindoles by Quinone-Carbonate Synergistically Triggered Intermolecular Radical Coupling.

The Journal of organic chemistry·2024
Same author

Effective separation of dyes/salts by sulfonated covalent organic framework membranes based on phenolamine network conditioning.

RSC advances·2024
Same author

GABAergic interneurons in the hippocampal CA1 mediate contextual fear generalization in PTSD rats.

Journal of neurochemistry·2024

関連する実験動画

Updated: Feb 6, 2026

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene
09:16

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene

Published on: May 20, 2019

8.2K

高立体障害および官能基化されたC(sp3)-N結合を構築するための穏やかなプロトコル

Yifei Jiang1, Lili Wu1, Chengming Wang1

  • 1College of Chemistry and Materials Science, Jinan University, Guangzhou, Guangdong 511443, China.

The Journal of organic chemistry
|February 5, 2026
PubMed
まとめ
この要約は機械生成です。

新規の遷移金属フリーアルキル化法を用いて、立体障害および官能基化されたアミンを合成しました。このアプローチは、価値のあるアミン化合物のための穏やかで効率的なルートを提供します。

キーワード:
アミン合成遷移金属フリーアルキル化立体障害官能基化

さらに関連する動画

An Unpredictable Chronic Mild Stress Protocol for Instigating Depressive Symptoms, Behavioral Changes and Negative Health Outcomes in Rodents
06:55

An Unpredictable Chronic Mild Stress Protocol for Instigating Depressive Symptoms, Behavioral Changes and Negative Health Outcomes in Rodents

Published on: December 2, 2015

23.5K
Investigations on Alterations of Hippocampal Circuit Function Following Mild Traumatic Brain Injury
10:59

Investigations on Alterations of Hippocampal Circuit Function Following Mild Traumatic Brain Injury

Published on: November 19, 2012

15.9K

関連する実験動画

Last Updated: Feb 6, 2026

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene
09:16

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene

Published on: May 20, 2019

8.2K
An Unpredictable Chronic Mild Stress Protocol for Instigating Depressive Symptoms, Behavioral Changes and Negative Health Outcomes in Rodents
06:55

An Unpredictable Chronic Mild Stress Protocol for Instigating Depressive Symptoms, Behavioral Changes and Negative Health Outcomes in Rodents

Published on: December 2, 2015

23.5K
Investigations on Alterations of Hippocampal Circuit Function Following Mild Traumatic Brain Injury
10:59

Investigations on Alterations of Hippocampal Circuit Function Following Mild Traumatic Brain Injury

Published on: November 19, 2012

15.9K

科学分野:

  • 有機化学
  • 合成方法論

背景:

  • アミンは医薬品および材料科学における重要な構成要素です。
  • 立体障害および官能基化されたアミンの合成には、しばしば過酷な条件または高価な触媒が必要です。

研究 の 目的:

  • 新規の遷移金属フリーで立体障害および官能基化されたアミンを合成する方法を開発すること。
  • アミン構築のための穏やかで効率的な反応条件を確立すること。

主な方法:

  • 遷移金属フリーのアプローチを用いたアミンのアルキル化。
  • 最適な収率と選択性のための反応条件の探索。

主要な成果:

  • 様々な立体障害および官能基化されたアミンの合成に成功しました。
  • 穏やかな条件下での遷移金属フリーアルキル化の実現可能性を実証しました。
  • 関与している可能性のある反応性共役アニオン中間体を特定しました。

結論:

  • 開発された方法は、価値のあるアミン誘導体へのアクセス可能で効率的なルートを提供します。
  • この遷移金属フリー戦略は、アミン合成のためのより環境に優しい代替手段を提供します。