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Updated: Feb 14, 2026

Deacetylation Assays to Unravel the Interplay between Sirtuins SIRT2 and Specific Protein-substrates
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ペンタフルヴェン-ラジアレンサイクロアディションにおけるアンビモダルのペリセレクティビティを解明:幾何学,電荷分散,反応力学の相互作用

Rama Krishna Kadiyam1, Akanksha Ashok Sangolkar1, Sandhya Madem1

  • 1Laboratory of Advanced Computation and Theory for Materials and Chemistry, Department of Chemistry, National Institute of Technology Warangal (NITW), Warangal, Telangana 506004, India.

The journal of physical chemistry. A
|February 12, 2026
PubMed
まとめ

この研究は,ペンタフルヴェンと[n]ラジアルエンがどのように両方向に反応し,ダイナミックな効果により複数の製品を形成するかを明らかにしています. [5]-ラジアルエンは,電子的および幾何学的要因によって制御される,最も両方向反応性を示しています.

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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