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Ni-Co-Crの多元元素合金におけるアル誘発の異常な粒子の成長
Kexuan Zhou1, Siqi Wu1, Yan Zhou1
1The First Aircraft Institute, Aviation Industry Corporation of China, Xi'an 710089, China.
Materials (Basel, Switzerland)
|February 13, 2026
まとめ
アルミニウム添加は,面中心立方体 (FCC) 多主元素合金 (MPEA) での粒子の成長を加速します. しかし,ボルンガムとモリブデンの添加物は,活性化エネルギーを増加させることで,この急速な穀物の成長を阻害します.
科学分野:
- マテリアルサイエンス 材料科学
- メタルルジーは,金属の製造業です.
- 物理化学 物理化学について
背景:
- 代替元素は,固体溶液と第2相強化を通じて,面中心立方体 (FCC) 多主元素合金 (MPEA) の機械的性質を高めます.
- 原子半径が大きい合金元素は,典型的には格子歪みを誘導し,マトリックス強化のための穀物境界移動を妨げます.
研究 の 目的:
- アルミニウム (Al),ボルンガム (W),およびモリブデン (Mo) がNi-Co-CrベースのMPEAsで穀物成長運動に与える影響を調査する.
- これらの置換要素が穀物の境界移動と微細構造の進化に影響を与えるメカニズムを解明する.
主な方法:
- 体系的な冷却実験は,異なるAl,W,Mo含有量を持つMPEAsで実施されました.
- 定量的な穀物成長分析を用いて,穀物境界移動への影響を分析した.
- 粒子の成長のための活性化エネルギーは,溶質効果を評価するために計算されました.
主要な成果:
- 代用アルは,穀物の成長のための活性化エネルギーを219kJ/molに低下させ,穀物の境界移動性を高め,異常な穀物の成長につながることが判明しました.
- WとMoのわずかな添加は,穀物の成長のための活性化エネルギーを251kJ/molに増加させ,Al誘発の急速な穀物の成長を効果的に抑制しました.
- 穀物の成長成分 (n) は,特定の成長メカニズムを示唆するAlで2であることが観察されましたが,WとMoはより高い成分をもたらしました.
結論:
- 置換溶液は,MPEAにおける穀物の成長運動を制御する上で重要な役割を果たします.
- Alは穀物境界の移動性を促進し,WとMoは阻害剤として作用し,MPEAの微細構造を調整するための経路を提供します.
- これらの溶解物効果を理解することは,望ましい機械的性質を持つMPEAを設計する上で極めて重要です.
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