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Updated: Feb 17, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
08:25

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

Published on: January 17, 2020

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協調幾何学指向光学アニソトロピーと,キラル金属有機フレームワークにおける相対応非線形光学

Xinchao Wang1,2, Zhaoxing Wang1,2, Shumei Chen1

  • 1College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, P. R. China.

Inorganic chemistry
|February 16, 2026
PubMed
まとめ

研究者は,非線形光学 (NLO) アプリケーションの光学アニソトロピーと相対応を強化するために,キラル金属有機フレームワーク (CMOF) を開発しました. 異なる金属の中心は,異なる協調幾何学を達成し,二重断裂と第二ハーモニー生成効率を高めました.

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Stereoisomerism

Isomerism in Complexes
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Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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