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Updated: Feb 19, 2026

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
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Published on: September 12, 2018

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サイクロヘキセンの選択的酸化脱水化により,TiO2上で1,3-サイクロヘキサジエンに

Tianyue Wang1, Xinning Gu1, Zhiyong Xiao1

  • 1Shenzhen Key Laboratory of Energy Chemistry & Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong 518055, P. R. China.

The journal of physical chemistry letters
|February 17, 2026
PubMed
まとめ

炭化水素脱水化における選択的C-H結合の活性化が難しい. この研究では,ルチルTiO2でサイクロヘキセンの脱水化が示され,表面酸素種を含む異なる熱およびUV誘発経路経由で1,3-サイクロヘキサディエンが得られます.

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