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Updated: Feb 19, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
08:25

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Published on: January 17, 2020

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アゾベンゼン機能化された金属有機多面体によって可能になった同質的および異質的触媒の間の光交互変換

Shu Shi1, Mengmeng Zhang2, Manish Kumar Dinker1

  • 1State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, China.

Nano letters
|February 18, 2026
PubMed
まとめ

研究者らは光に反応する金属有機多面体 (MOP) を開発し,均質と異質の触媒を切り替えた. このイノベーションは,高触媒活性と容易な分離を組み合わせる新しい方法を提供し,触媒の重要な課題に取り組んでいます.

キーワード:
アゾベンゼン (AZOBENZENE) とは異質なカタリシスである.均質なカタリシスである.メタル・オーガニック・ポリヘッドフォトスイッチ可能な変換

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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