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Updated: May 10, 2026

Synthesis and Reaction Chemistry of Nanosize Monosodium Titanate
08:44

Synthesis and Reaction Chemistry of Nanosize Monosodium Titanate

Published on: February 23, 2016

チタンによるケトンの脱酸素化フォスフォン化

Yuquan Wang1, Kai Yin2, Xiaobo Pang1

  • 1State Key Laboratory of Natural Product Chemistry (SKLAOC), College of Chemistry and Chemical Engineering, Lanzhou University 222 South Tianshui Road Lanzhou 730000 China shuxingzh@lzu.edu.cn.

Chemical science
|February 20, 2026
PubMed
まとめ

この研究では,チタン複合体とマンガン粉末を用いたC(sp3) -P結合のための新しい方法が紹介されています. このアプローチは,ケトンとフォスフィン酸化物を効率的に結びつけ,合成化学を前進させます.

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Aldehydes and Ketones to Alkanes: Wolff–Kishner Reduction

Wolff–Kishner reduction involves converting aldehydes and ketones to alkanes using hydrazine and a base. The reaction converts a carbonyl group to a methylene group. The method was independently discovered by N. Kishner in 1911 and L. Wolff in 1912. The reduction is carried out in high-boiling solvents such as ethylene glycol and diethylene glycol because heat is required to deprotonate the N–H proton in one of the reaction steps.
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