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Updated: Feb 25, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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末端アルケンのマルコヴニコフの水素アミネーションは,フォスフィン・レドックス・カタリシスによるものです

Flora Fan1, Kassandra F Sedillo2, Alexander J Maertens1

  • 1Department of Chemistry & Biochemistry, University of California, Los Angeles, California, USA.

Nature
|February 23, 2026
PubMed
まとめ

研究者らは,アルケンのマルコヴニコフニコフによる水酸化酸化のための新しいフォスフィン-フォトレドックス触媒を開発しました. このメイングループ触媒アプローチは,移行金属の反応性を模倣し,新しい合成経路を可能にします.

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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