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関連する概念動画

Phase Transitions02:31

Phase Transitions

Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to occupy...
Phase Transitions: Vaporization and Condensation02:39

Phase Transitions: Vaporization and Condensation

The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
Phase Transitions: Sublimation and Deposition02:33

Phase Transitions: Sublimation and Deposition

Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
Phase Transitions01:21

Phase Transitions

A phase transition is the process in which a substance changes from one state of matter to another, like from a solid to a liquid, liquid to gas, or vice versa, at a specific temperature and under given pressure conditions. This change is spontaneous and is affected by alterations in temperature and pressure. These parameters impact the strength of the forces between molecules (intermolecular forces) in the substance.During a phase transition, both the initial and final phases of the substance...
Transition Zone01:28

Transition Zone

The transition zone in concrete is a critical area where aggregate meets cement paste, marked by a distinct porosity and weakness compared to the surrounding material. The adhesion around the aggregates is primarily due to Van Der Waals forces. The voids within this zone influence its robustness; initially, it is less durable than the surrounding bulk mortar due to larger voids. Initially, when concrete is compacted, a higher water-cement ratio near the aggregates leads to the formation of...

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Micro 3D Printing Using a Digital Projector and its Application in the Study of Soft Materials Mechanics
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乾燥パターンにおける基板温度駆動の微細構造遷移

Sanjib Majumder1,2, Madivala G Basavaraj1,2, Dillip K Satapathy1,3,2

  • 1Soft Materials Laboratory, Department of Physics, IIT Madras, Chennai, Tamil Nadu 600036, India.

Langmuir : the ACS journal of surfaces and colloids
|February 24, 2026
PubMed
まとめ

ポリ(N-イソプロピルアクリルアミド)(PNIPAM)マイクロゲルは、流体界面で規則的な単分子層を形成し、コロイド膜の作製を可能にする。その温度応答挙動は複雑な堆積パターンを決定し、調整可能な材料特性を提供する。

キーワード:
マイクロゲル自己組織化コロイド薄膜堆積パターン温度応答性材料科学

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科学分野:

  • ソフトマター物理学
  • コロイド科学
  • 材料科学

背景:

  • ポリ(N-イソプロピルアクリルアミド)(PNIPAM)マイクロゲルは、調整可能な膨潤挙動を持つ刺激応答性コロイドである。
  • マイクロゲルは、バルクと比較して流体-流体界面で異なる速度論を示し、平坦化して規則的な単分子層を形成する。
  • この界面挙動は、コロイド膜とパターン化構造を作製する経路を提供する。

主な方法:

  • 制御された温度下での親水性基板上へのPNIPAMマイクロゲル含有水性液滴の乾燥。
  • ビデオ顕微鏡と接触角ゴニオメトリを用いた液滴蒸発動力学のその場モニタリング。
  • 原子間力顕微鏡(AFM)を用いた乾燥マイクロゲル堆積物形態の特性評価。

結論:

  • PNIPAMマイクロゲルは、乾燥条件と温度を制御することによって、多様な構造にパターン化できる。
  • 温度は、蒸発中のマイクロゲル界面活性と自己組織化を調節する上で重要な役割を果たす。
  • 本研究は、温度応答性マイクロゲルを用いた調整可能なコロイド膜の作製方法を示す。