関連する実験動画

Updated: Feb 26, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production

Published on: December 6, 2021

中空炭素上の原子分散Ru-Coペアを酸性酸素発生反応の堅牢な触媒として利用

Fengqin Zhang¹, Qingmei Wang¹, Zhijie Chen²

¹Guizhou University Key Laboratory of Green Chemical and Clean Energy Technology, Guizhou University Engineering Research Center of Efficient Utilization for Industrial Waste, School of Chemistry and Chemical Engineering, Guizhou University, Institute of Dual-carbon and New Energy Technology Innovation and Development of Guizhou Province, Guiyang, Guizhou, 550025, China. qmwang3@gzu.edu.cn.

Chemical communications (Cambridge, England)

|February 24, 2026

Abstract:

Developing durable, high-activity acidic oxygen evolution catalysts remains difficult. Here, we present atomically dispersed, spatially neighboring Ru-Co pairs anchored on hollow S,N-doped carbon via robust coordination. RuCo/SNC achieves a superior overpotential of 230 mV at 10 mA cm^-2 and remarkable stability compared to RuO₂. Operando spectroscopy detects concurrent *OOH and *O-O intermediates, revealing a mechanism where adsorbate evolution coexists with moderated lattice oxygen participation. This cooperative pathway significantly suppresses metal leaching. Consequently, engineering anchored, electronically coupled Ru-Co pairs provides an effective strategy to regulate reaction pathways and overcome activity-stability trade-off in acidic oxygen evolution.

キーワード:

酸素発生反応ルテニウム-コバルト原子分散触媒炭素触媒酸性耐久性電気化学触媒材料科学

さらに関連する動画

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

Published on: April 10, 2018

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction

Published on: August 23, 2018

関連する概念動画

Oxidative Cleavage of Alkenes: Ozonolysis

Oxidative Cleavage of Alkenes: Ozonolysis

In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.

Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate

Alkenes can be dihydroxylated using potassium permanganate. The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.

Oxidation-Reduction Reactions

Oxidation-Reduction Reactions

Oxidation–Reduction Reactions

Oxymercuration-Reduction of Alkenes

Oxymercuration-Reduction of Alkenes

Oxymercuration–reduction of alkenes is one of the major reactions converting alkenes to alcohols. It involves the hydration of alkenes with mercuric acetate in a mixture of tetrahydrofuran and water, forming an organomercury adduct. This is followed by a demercuration step in which the adduct is reduced to an alcohol using sodium borohydride.