高機能配位子エンジニアリングによる高性能CsPb(Br/Cl)₃ナノ結晶を用いた高効率・高安定性純青色ペロブスカイトLED

The development of pure-blue perovskite light-emitting diodes (PeLEDs) still lags behind that of green and red-emitting PeLEDs. Mixed halide (Br/Cl) perovskite nanocrystals (PeNCs) are commonly employed for blue emission but suffer from halide vacancies and ion migration. Here, we present a passivation strategy using the multifunctional fluorinated phosphonic acid molecule (1H,1H,2H,2H-heptadecafluorodec-1-yl)phosphonic acid (HFPA), which possesses active functional groups that improve the stability and electroluminescence performance of CsPb(Br/Cl)₃ NCs. The HFPA molecule is shown to interact with uncoordinated Pb²⁺ on the PeNC surface through the phosphonate groups, concurrently establishing hydrogen bonds with adjacent halide ions. Moreover, the presence of fluorine atoms promotes ionic bond formation with the halide octahedra, thereby stabilizing the octahedral structure. The fabricated PeNC-LEDs exhibited a spectrally stable pure-blue emission peak at 467 nm, achieving a significantly improved external quantum efficiency (14.8%, 9-fold higher), maximum luminance (1052 cd·m^-2, 10-fold higher), and half-life (342 s, 13-fold higher) compared to the device fabricated with unmodified CsPb(Br/Cl)₃ NCs. Furthermore, the effective passivation of surface vacancies and stabilization of halogen ions by the HFPA molecules successfully suppressed ion migration in the PeNC-LEDs, thereby significantly enhancing the stability of the device.