通过乙的部分氧化对乙烯具有很高的选择性
1Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455, USA. Departmento di Chemica Industriale e Ingegneria Chemica, Politechnico di Milano, Milan, Italy.
概括
在以部分氧化过程中用-锡催化剂添加,可以在高转化率 (>70%) 达到高乙烯选择性 (>85%). 这种方法避免了爆炸性混合物,并最大限度地减少了CO和CO2等不必要的副产品.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 催化剂是一种催化剂.
- 氧化反应 氧化反应
背景情况:
- 乙烯生产主要依赖于能源密集型蒸汽裂解.
- 由于形成CO和CO2的竞争反应,乙对乙烯的选择性氧化具有挑战性.
- 高温反应通常有利于平衡产品,使乙烯 (非平衡产品) 难以获得高产量.
研究的目的:
- 开发一种高选择性工艺,通过乙部分氧化生产乙烯.
- 为了研究添加对乙氧化在-锡催化剂上的影响.
- 探索这种方法作为蒸汽裂解的替代方法的潜力.
主要方法:
- 在950°C使用-锡催化剂对乙进行部分氧化.
- 在乙/氧反应混合物中添加大量的 (H2).
- 控制反应参数,包括温度,接触时间 (约. 10^-3秒),以及反应物比率.
主要成果:
- 在超过70%的乙转化时,达到超过85%的乙烯选择性.
- 显著抑制一氧化碳 (CO) 和二氧化碳 (CO2) 的形成,使其产量从20%降至5%.
- 没有观察到火焰或爆炸,尽管在乙的存在下使用了潜在的爆炸性H2/O2混合物.
结论:
- 在Pt-Sn催化剂上对乙部分氧化添加是一种高度有效的选择性乙烯生产方法.
- 该过程运行安全,产生更多的比消耗,允许一个可回收的系统.
- 这种催化方法在取代工业乙烯合成的传统蒸汽裂解方面显著有前途.
相关概念视频
Oxidations of Aldehydes and Ketones to Carboxylic Acids
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Aldehydes readily undergo oxidation in strong oxidizing agents such as potassium permanganate and chromic acid. The oxidation can also be carried out using mild oxidizing agents such as silver oxide. In fact, aldehydes can be easily oxidized...
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Baeyer–Villiger oxidation converts aldehydes to carboxylic acids and ketones to esters. The reaction uses peroxy acids or peracids and is often catalyzed by acid. The reaction is named after its pioneers, Adolf von Baeyer and Victor Villiger. The reaction is achieved by a wide range of peracids such as m-chloroperoxybenzoic acid (mCPBA), perbenzoic acid (C6H5COOOH), peracetic acid (CH3COOOH), hydrogen peroxide (H2O2), and tert-butyl hydroperoxide (t-BuOOH).
The carbonyl center is activated by...
The carbonyl center is activated by...
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Stability of Conjugated Dienes
Introduction
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Vicinal Diols via Reductive Coupling of Aldehydes or Ketones: Pinacol Coupling Overview
Wilhelm Rudolph Fittig discovered the pinacol coupling reaction in 1859. It is a radical dimerization reaction and involves the reductive coupling of aldehydes or ketones in the presence of hydrocarbon solvent to yield vicinal diols.
Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction
The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.


