在水性NaCl气溶上进行离子增强界面化学的实验和模拟

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In Situ SIMS and IR Spectroscopy of Well-defined Surfaces Prepared by Soft Landing of Mass-selected Ions
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In Situ SIMS and IR Spectroscopy of Well-defined Surfaces Prepared by Soft Landing of Mass-selected Ions

Published on: June 16, 2014

Knipping1, Lakin, Foster

  • 1Department of Mechanical and Aerospace Engineering, Department of Chemistry, University of California, Irvine, Irvine, CA 92697, USA. J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, 18223, Pragu.

Science (New York, N.Y.)
|April 15, 2000
PubMed
概括

缩盐颗粒在空气-水界面的反应是理解大气化学的关键. 离子增强相互作用显著影响盐溶液中的气体反应.

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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...