古代的硫循环和大气氧气的早期历史
D E Canfield1, K S Habicht, B Thamdrup
1Danish Center for Earth System Science (DCESS) and Institute of Biology, Odense University, SDU, Campusvej 55, 5230 Odense M, Denmark. dec@biology.ou.dk
概括
沉积硫同位素揭示了早期的地球.
科学领域:
- 地质化学 地质化学
- 古气候学 古气候学
- 微生物学 微生物学
背景情况:
- 大气中氧气积累的历史对于了解早期生命至关重要.
- 沉积岩中的硫同位素提供了古代环境条件的代理.
研究的目的:
- 为了研究在高温下微生物硫酸盐还原过程中硫的同位素分离.
- 确定硫酸盐降解率如何影响沉积物中同位素特征的保存.
- 为了重建大气氧和海水硫酸盐度在古代和原生代的演变.
主要方法:
- 在微生物硫酸盐减少实验中测量了硫同位素分离,温度高达88°C.
- 分析了古代岩石构成中的沉积硫同位素记录.
- 模拟了硫酸盐减少率对同位素保存的影响.
主要成果:
- 在微生物硫酸盐减少过程中,在高达88°C的温度下观察到硫的同位素分离.
- 硫酸盐的降解率显著影响到生物硫同位素分离的保存.
- 沉积硫同位素记录表明,海水硫酸盐和大气氧气水平在早期的阿尔开纪 (3.42.8亿年前) 很低.
结论:
- 早期的阿尔凯时大气和海洋只有有限的氧气和硫酸盐.
- 大气中氧气和海水硫酸盐的大量积累始于早期的原生纪 (2.50.54亿年前).
- 硫同位素地质化学是重建地球早期生物地质化学循环的强大工具.
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