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相关概念视频

Structures of Solids02:22

Structures of Solids

Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Structure of Alkanes02:23

Structure of Alkanes

The formation of carbon-carbon bonds leading to the creation of the carbon chain is the basis of organic chemistry. August Kekulé and Archibald Scott Couper independently developed this idea of carbon chain formation.
Hydrocarbons are the simplest organic compounds composed of carbons and hydrogens. Based on the bond order between carbons, the hydrocarbons are further classified into alkanes, alkenes, and alkynes. 
Alkanes are the simplest hydrocarbons with sp3 hybrid carbon atoms. These sp3...
Structure and Bonding of Alkenes02:47

Structure and Bonding of Alkenes

Olefins, which are unsaturated hydrocarbons containing one or more carbon–carbon double bonds, are broadly divided into alkenes and cycloalkenes. The general chemical formula of an alkene is CnH2n.
Doubly bonded carbons are sp2 hybridized and have a trigonal planar geometry. The double bond is composed of a σ bond formed by the overlap of hybrid orbitals and a π bond produced by the lateral overlap of unhybridized 2p orbitals on both the carbons. Each carbon atom is bonded to two hydrogen atoms...
Structure and Physical Properties of Alkynes02:37

Structure and Physical Properties of Alkynes

Introduction:
In nature, compounds containing both carbon and hydrogen are known as "hydrocarbons". Aliphatic hydrocarbons are compounds whose molecules contain saturated single bonds (i.e., alkanes) or unsaturated double or triple bonds. Alkenes contain carbon–carbon double bonds and have a structural formula CnH2n. Unsaturated hydrocarbons containing carbon–carbon triple bonds are called "alkynes" and are structurally represented by the formula CnH2n-2.
The simplest alkyne is ethyne, or...
Structure of Amines01:19

Structure of Amines

The hybridized nitrogen atom in amines possesses a lone pair of electrons and is bound to three substituents with a bond angle of around 108°, which is less than the tetrahedral angle of 109.5°. However, the C–N–H bond angle is slightly larger at 112°, with a carbon–nitrogen bond length of 147 pm. This carbon–nitrogen bond length of of amines is longer than the carbon–oxygen bond of alcohols (143 pm) but shorter than alkanes’ carbon–carbon bond (154 pm). These aspects are illustrated in Figure...

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相关实验视频

Updated: Jul 14, 2026

Facile Preparation of Ultrafine Aluminum Hydroxide Particles with or without Mesoporous MCM-41 in Ambient Environments
05:50

Facile Preparation of Ultrafine Aluminum Hydroxide Particles with or without Mesoporous MCM-41 in Ambient Environments

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水合的α-Al(2)O(3) (0001) 表面的结构.

Eng1, Trainor, Brown

  • 1Consortium for Advanced Radiation Sources, The University of Chicago, Chicago, IL 60637, USA. Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115, USA. Stanford Synchrotron Radiation Laboratory, Sta.

Science (New York, N.Y.)
|May 12, 2000
PubMed
概括

含水的α- (0001) 表面是氧终端的,不同于干净的,终端的表面. 这种水合结构影响了氧化的反应性.

科学领域:

  • 表面科学是一门科学.
  • 材料科学是一种材料科学.
  • 化学 化学 化学

背景情况:

  • 氧化表面的物理和化学特性对于理解其反应性至关重要.
  • 在水的存在下,alpha-Al(2)O(3) (0001) 表面的行为是其应用的关键.

研究的目的:

  • 为了确定水合的α-Al{2}O{3} (0001) 表面的原子结构.
  • 为了比较水合的表面结构和干净的表面结构.

主要方法:

  • 使用同步 X 射线辐射进行晶体剪切杆衍射.
  • 在水蒸气下以 300 克尔文的温度进行现场表面分析.

主要成果:

  • 水合的α-Al(2)O(3) (0001) 表面是氧终端的,下面有一个收缩的层.
  • 一个被吸附的水层被确定在地表上方大约2.3安格斯特罗姆.
  • 水合结构代表了α-Al(2) O(3) 和gamma-Al(OH) ((3) 之间的中间体.
  • 清洁的alpha-Al(2)O(3) (0001) 表面是终端和放松的.

结论:

  • 含水和清洁的α-Al(2) O(3) (0001) 表面表现出不同的结构.

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Facile Preparation of Ultrafine Aluminum Hydroxide Particles with or without Mesoporous MCM-41 in Ambient Environments
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Simultaneous Multi-surface Anodizations and Stair-like Reverse Biases Detachment of Anodic Aluminum Oxides in Sulfuric and Oxalic Acid Electrolyte
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  • 这些结构差异解释了清洁与氧化表面的不同反应性.