在单壁碳纳米管内形成的一维晶体的离散原子成像
Meyer1, Sloan, Dunin-Borkowski
1Department of Materials Science, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ, UK. Wolfson Catalysis Centre (Carbon Nanotechnology Group), Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR, UK.
概括
研究人员确定了碳纳米管内化晶体的晶体学. 由于受限效应,晶体结构与散装材料有很大不同.
科学领域:
- 材料科学 材料科学 材料科学
- 晶体学 晶体学是指结晶学.
- 纳米技术纳米技术
背景情况:
- 酸 (KI) 通常形成在批量晶体结构中.
- 将材料限制在单壁碳纳米管中可以改变它们的特性.
研究的目的:
- 为了确定一个一维的化晶体的晶体学.
- 为了研究碳纳米管内封装引起的结构变化.
主要方法:
- 使用了高分辨率传输电子显微镜 (HRTEM).
- 用相成像和修改的焦点序列恢复来重建原子位置.
- 在封闭晶体内的格子间距的分析.
主要成果:
- 确定了1.6纳米SWCNT内的1D KI晶体的完整晶体学.
- 个别的和原子被分解.
- 观察到的格子间距与批量KI显著不同.
- 结构差异归因于表面原子协调减少和纳米管接近.
结论:
- 纳米管封装诱导化晶体的显著结构变化.
- 表面原子协调和范德瓦尔斯相互作用在封闭的晶体结构中起着至关重要的作用.
- HRTEM对于纳米材料的原子层次表征是有效的.
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