Jove
Visualize
联系我们
JoVE
x logofacebook logolinkedin logoyoutube logo
关于 JoVE
概览领导团队博客JoVE 帮助中心
作者
出版流程编辑委员会范围与政策同行评审常见问题投稿
图书馆员
用户评价订阅访问资源图书馆顾问委员会常见问题
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experiments存档
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教师资源中心教师网站
使用条款与条件
隐私政策
政策

相关概念视频

Oxidation Numbers03:14

Oxidation Numbers

In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
Alkali Metals03:06

Alkali Metals

Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide02:44

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate02:21

Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate

Alkenes can be dihydroxylated using potassium permanganate. The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids02:04

Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

Diols are compounds with two hydroxyl groups. In addition to syn dihydroxylation, diols can also be synthesized through the process of anti dihydroxylation. The process involves treating an alkene with a peroxycarboxylic acid to form an epoxide. Epoxides are highly strained three-membered rings with oxygen and two carbons occupying the corners of an equilateral triangle. This step is followed by ring-opening of the epoxide in the presence of an aqueous acid to give a trans diol.
Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.

您也可能阅读

相关文章

通过共同作者、期刊和引用图与本文相关的文章。

排序
Same author

Positional changes of maxillary central incisors following orthodontic treatment using single-crown implants as fixed reference markers.

Clinical oral implants research·2017
Same author

Non-intercepted dose errors in prescribing anti-neoplastic treatment: a prospective, comparative cohort study.

Annals of oncology : official journal of the European Society for Medical Oncology·2015
Same author

Glucagon stimulation test for estimating endogenous insulin secretion in dogs.

The Veterinary record·2008
Same author

Implants and/or teeth: consensus statements and recommendations.

Journal of oral rehabilitation·2008
Same author

Treatment of severe hypodontia-oligodontia--an interdisciplinary concept.

International journal of oral and maxillofacial surgery·2007
Same author

Epidermal growth factor receptor gene copy number and protein level are not associated with outcome of non-small-cell lung cancer patients treated with chemotherapy.

Annals of oncology : official journal of the European Society for Medical Oncology·2006

相关实验视频

Updated: Jun 29, 2026

Production of Synthetic Nuclear Melt Glass
04:36

Production of Synthetic Nuclear Melt Glass

Published on: January 4, 2016

材料科学. 材料科学. 这是已知最硬的氧化物.

L S Dubrovinsky1, N A Dubrovinskaia, V Swamy

  • 1Institute of Earth Sciences, Uppsala University, S-752 36 Uppsala, Sweden. leonid.dubrovinsky@geo.uu.se

Nature
|April 5, 2001
PubMed
概括

研究人员发现了一种新的二氧化 (TiO2) 多态体,具有cotunnite结构. 这种在极端条件下合成的超硬氧化物是已知的最硬的氧化物材料.

科学领域:

  • 材料科学 材料科学 材料科学
  • 矿物物理 矿物物理
  • 固态化学 固态化学

背景情况:

  • 寻找超硬材料的研究仍在继续,氧化物通常与钻石等非氧化物相比,硬度较低.
  • 之前的研究已经探索了各种二氧化 (TiO2) 多态,但没有一个接近已知的超硬材料的硬度.

研究的目的:

  • 为了合成和描述一种新的,超硬的二氧化 (TiO2) 多态体.
  • 在高压和高温下研究这种新氧化相的结构和机械性能.

主要方法:

  • 使用多或钻石细胞进行高压合成实验.
  • 在现场表征技术,如X射线衍射 (XRD) 来确定晶体结构.
  • 计算建模用于预测和确认材料属性.

主要成果:

  • 发现了一种新的cotunnite结构的氧化 (TiO2) 多态.
  • 在压力超过60千兆帕克 (GPa) 和温度超过1000凯尔文 (K) 的情况下实现合成.
  • 新阶段表现出异常硬度和低可压缩性,将其归类为已知最硬的氧化物.

结论:

  • 鉴定到的以cotunnite结构的氧化代表了超硬材料领域的重大进步.

更多相关视频

Bulk and Thin Film Synthesis of Compositionally Variant Entropy-stabilized Oxides
09:41

Bulk and Thin Film Synthesis of Compositionally Variant Entropy-stabilized Oxides

Published on: May 29, 2018

Determining the Mechanical Strength of Ultra-Fine-Grained Metals
05:04

Determining the Mechanical Strength of Ultra-Fine-Grained Metals

Published on: November 22, 2021

相关实验视频

Last Updated: Jun 29, 2026

Production of Synthetic Nuclear Melt Glass
04:36

Production of Synthetic Nuclear Melt Glass

Published on: January 4, 2016

Bulk and Thin Film Synthesis of Compositionally Variant Entropy-stabilized Oxides
09:41

Bulk and Thin Film Synthesis of Compositionally Variant Entropy-stabilized Oxides

Published on: May 29, 2018

Determining the Mechanical Strength of Ultra-Fine-Grained Metals
05:04

Determining the Mechanical Strength of Ultra-Fine-Grained Metals

Published on: November 22, 2021

  • 这一发现突破了已知的氧化物硬度的界限,为新的技术应用提供了潜力.
  • 需要对高压氧化多态的合成和特性进行进一步的研究.