液晶在碳质表面上的排列与方向顺序
J Stohr1, M G Samant, J Luning
1IBM Research Division, Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA.
概括
在碳表面上的液晶对齐是通过控制表面键序来实现的. 近边缘X射线吸收细结构 (NEXAFS) 光谱揭示了方向顺序如何指导液晶对齐.
科学领域:
- 材料科学 材料科学 材料科学
- 表面科学是一门学科.
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 液晶 (LC) 调整层对于显示技术至关重要.
- 碳质表面是LC对齐层的潜在候选者.
- 了解表面特性和LC对齐之间的关系至关重要.
研究的目的:
- 为了研究碳质表面的定向键序与液晶对齐方向之间的联系.
- 建立用于使用无形碳膜作为LC对齐层的科学基础.
主要方法:
- 使用近边缘X射线吸收细结构 (NEXAFS) 光谱.
- 分析了三种类型的碳状表面:磨聚胺,离子束辐射聚胺和离子束辐射钻石状碳膜.
主要成果:
- 证明了碳质表面的定向键顺序与LC对齐方向之间的直接相关性.
- 证明,通过工程表面定向顺序,几乎可以在任何碳质基板上诱导LC对齐.
结论:
- 表面定向顺序是决定碳基板上LC对齐方向的关键因素.
- 无形碳膜的定向低能离子束处理可以创建有效的LC对齐层.
- 这项研究为开发先进的LC对齐材料提供了基础.
相关概念视频
Structures of Solids
17.8K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
17.8K
Metallic Solids
16.4K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and...
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and...
16.4K
Crystal Field Theory - Octahedral Complexes
28.4K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
28.4K
Chair Conformation of Cyclohexane
16.2K
The chair conformation is the most stable form of cyclohexane due to the absence of angle and torsional strain. The absence of angle strain is a result of cyclohexane’s bond angle being very close to the ideal tetrahedral bond angle of 109.5° in its chair conformer. Similarly, the torsional strain is also absent owing to the perfectly staggered arrangement of bonds.
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this...
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this...
16.2K
Polymer Classification: Crystallinity
3.1K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
3.1K
Determination of Crystal Structures
135
In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...
135


