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Updated: Jun 24, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 21, 2014

在Pd催化与一氧化碳交替共聚化中,主要是1,2-插入 styrene

K Nozaki1, H Komaki, Y Kawashima

  • 1Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501 Japan.

Journal of the American Chemical Society
|July 18, 2001
PubMed
概括

这项研究揭示了与其他配体形成对比的,在催化与CO的共聚合中,烯的1,2-插入是独有的. 这种区域选择性防止β-化物消除,使得可控的聚合物链生长.

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