高光二环金属化复合物:合成,光物理特性和在有机发光二极管中使用
S Lamansky1, P Djurovich, D Murphy
1Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA.
Journal of the American Chemical Society
|July 18, 2001
概括
这项研究报告了新的循环金属化 (((III) 复合物,这些复合物在整个颜色谱中有效地发射光. 这些复合物在有机发光二极管 (OLED) 中作为剂使用时表现出高性能.
科学领域:
- 有机金属化学 有机金属化学
- 材料科学 材料科学 材料科学
- 光物理学的光学物理学
- 有机电子 有机电子
背景情况:
- 循环金属化 (III) 复合物以其光发光特性而闻名.
- 在复合体中调整连接体可以改变它们的发射颜色和效率.
- 有机发光二极管 (OLED) 需要高效的发光材料来实现高性能.
研究的目的:
- 合成和研究一系列具有不同配体的环金属化 (III) 复合物.
- 调查光物理性质,包括光效率和寿命.
- 评估这些复合物的性能作为OLED设备中的剂.
主要方法:
- 合成含有C(***) N连接体和乙氨酸 (acac) 辅助连接体的环金属化 (III) 复合体.
- 光物理特征,包括测量量子产量和激发状态寿命.
- 制造和测试多层有机发光二极管 (OLED),使用合成的复合物作为补充剂.
主要成果:
- 合成的C(***) N2Ir(acac) 复合体表现出高光量子效率 (0.1-0.6) 和微秒寿命.
- 发射颜色可以通过修改C(***) N配体,从绿色调整为红色.
- 用三个特定的复合物 (ppy2Ir(acac),bt2Ir(acac),btp2Ir(acac)) 合的OLED实现了高的外部量子效率 (6-12.3%) 并显示出绿色,黄色和红色的电发光.
结论:
- 系统地修改C(***) N配体,可以在复合体中获得可调节的发射颜色.
- 这些复合体是高效的发射器,适合OLED应用.
- 开发的以为基础的OLED显示了一些报告中的最高效率,归因于高效的激子捕获和辐射放松.
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