含有四基 ((4-尼托) 甲的化合物:C-H...O网络,伪多态性和结构转变
R Thaimattam1, F Xue, J A Sarma
1School of Chemistry, University of Hyderabad, Hyderabad 500 046, India.
Journal of the American Chemical Society
|July 18, 2001
概括
甲在各种溶酸盐中表现出适应性的宿主网络结构. 它的灵活性,由弱相互作用驱动,允许在钻石形和方圆形晶体结构之间进行可逆转变.
科学领域:
- 晶体工程公司 晶体工程公司
- 超分子化学 超分子化学
- 材料科学 材料科学 材料科学
背景情况:
- 甲 ((4-尼托) 甲是一种具有显著结构适应性的新型宿主材料.
- 了解主机-客户互动对于设计功能性材料至关重要.
研究的目的:
- 为了研究四氧化 ((4-尼托) 甲溶酸盐的晶体结构.
- 根据主机-客户互动和网络拓学来对这些结构进行分类.
- 探索主机网络的动态行为.
主要方法:
- 单晶X射线对14个溶酸盐的衍射分析.
- 结构分类,分为三个不同的组.
- 变量温度研究观察结构转变.
主要成果:
- 确定了三个结构组:金刚形,方圆形和富含溶剂的.
- 这种由弱C-H...O和pi...pi相互作用形成的钻石状网络是前所未有的.
- 在THF溶解物中观察到的钻形和方形形状之间的可逆结构转变.
- 演示了溶剂去除和分辨能力.
结论:
- 甲 (Tetracis(4-nitrophenyl) 甲形成了一个具有强大和灵活特征的宿主网络.
- 主机网络的流动性归因于弱的连接相互作用.
- 这种适应性强的宿主材料具有在宿主-客户化学和材料设计中的应用潜力.
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